The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. TP10 A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority, is required. Energy storage capacity means the energy stored in a capacitor, as calculated according to the following equation. 441 For marine pollutants transported under UN3077, Environmentally hazardous substance, solid, n.o.s. or UN3082, Environmentally hazardous substance, liquid, n.o.s. and for purposes of shipping paper and package marking requirements, the technical name used in association with the basic description may be a proper shipping name listed in the 172.101 Hazardous Material Table; provided that the name chosen is not also an entry that includes n.o.s. as a part of the name or one that has a G in column (1) of the table. The following provisions also apply: a. A34 Aerosols containing a corrosive liquid in Packing Group II charged with a gas are not permitted for transportation by aircraft. 325 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. Other inorganic nitrate salts may replace part of the ammonium nitrate. The adsorption or absorption presents the following properties: (1) The pressure at a temperature of 20 C (68 F) in the receptacle is less than 0.6 bar (60 kPa); (2) The pressure at a temperature of 35 C (95 F) in the receptacle is less than 1 bar (100 kPa); (3) The pressure at a temperature of 85 C (185 F) in the receptacle is less than 12 bar (1200 kPa). For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Search & Navigation 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. Components classed as Division 6.1, Packing Group I, or Class 8, Packing Group I, must not be offered for transportation and transported under this description. Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. Heater pipes must be of welded construction designed for a test pressure of 500 psig. These provisions apply only to transportation in IBCs and Large Packagings. 8 A hazardous substance that is not a hazardous waste may be shipped under the shipping description Other regulated substances, liquid or solid, n.o.s., as appropriate. Uranium hexafluoride may be classified under this entry only if the conditions of 173.420(a)(4) and (6) and (d) and 173.421(b) and (d) of this subchapter, and, for fissile-excepted material, the conditions of 173.453 of this subchapter are met. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the subpart E (labeling) requirements of this part when offered for transportation by motor vehicle, rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in 173.62 of this subchapter, in conformance with the following conditions: a. This content is from the eCFR and is authoritative but unofficial. During transport, it must be protected from direct sunshine and stored (or kept) in a cool and well-ventilated place, away from all sources of heat. b. 139 Use of the special arrangement proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in 173.471, 173.472, or 173.473 of this subchapter. 127 Mixtures containing oxidizing and organic materials transported under this entry may not meet the definition and criteria of a Class 1 material. c. Completed neutron radiation detection systems containing detectors meeting the conditions of paragraph a of this special provision must be transported as follows: (1) The detectors must be contained in a strong sealed outer casing; (2) The casing must contain include sufficient absorbent or adsorbent material to absorb or adsorb the entire gas contents; (3) The completed system must be packed in strong outer packagings capable of withstanding a 1.8 meter (5.9 feet) drop test without leakage unless a system's outer casing affords equivalent protection. 440 When this material is transported by tank car, the offeror must ensure each tank car is remotely monitored for pressure and location. TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. It must be demonstrated that the article relieves its pressure by means of a fire degradable seal or other pressure relief device, in such a way that the pressure receptacle will not fragment and that the article or fragments of the article do not rocket more than 10 meters; and. Table 3 authorizes Large Packagings for specific proper shipping names through the use of IB Codes assigned in the 172.101 table of this subchapter. 343 A bulk packaging that emits hydrogen sulfide in sufficient concentration that vapors evolved from the sour crude oil can present an inhalation hazard must be marked as specified in 172.327. Based on the volatility class determined by using ASTM D 439 and the Reid vapor pressure (RVP) of the particular gasoline, the maximum lading pressure and maximum ambient temperature permitted during the loading of gasoline may not exceed that listed in Table I. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. b. Lithium batteries conforming to paragraph a. of this special provision must be assigned to UN Nos. TP20 This hazardous material must only be transported in insulated tanks under a nitrogen blanket. We recommend you directly contact the agency responsible for the content in question. Insulating materials may not promote corrosion to steel when wet. B56 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also authorized if the particle size of the hazardous material is not less than 149 microns. Outage must be sufficient to prevent tanks from becoming liquid full at 55 C (130 F). The Code of Federal Regulations (CFR) is the official legal print publication containing the codification of the general and permanent rules published in the Federal Register by the departments and agencies of the Federal Government. Lithium ion cells and batteries at a state of charge greater than 30 percent of their rated capacity may only be transported under conditions approved by the Associate Administrator in accordance with the requirements in 49 CFR part 107, subpart H. Guidance and methodology for determining the rated capacity can be found in sub-section 38.3.2.3 of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). 123 Any explosives, blasting, type C containing chlorates must be segregated from explosives containing ammonium nitrate or other ammonium salts. Alcoholic beverages containing more than 24 percent but not more than 70 percent alcohol by volume must be transported as materials in Packing Group III. The Associate Administrator may except from the requirements of this subchapter articles, machinery, and apparatus provided: a. d. All inner packagings placed inside bulk outer packagings must be blocked and braced to prevent shifting during transportation that could cause the container to open or fall over. Fertilizers meeting the criteria for this identification number are only subject to the requirements of this subchapter when offered for transportation and transported by air or vessel. All successfully conducted tests or reassignment to another compatibility group require the issuance of a new or revised approval by the Associate Administrator prior to transportation on or after the dates specified for each authorized mode of transport in this special provision. Special Provision Letter Codes Used in Hazmat Table, Column 7 Column 7 uses eight letter codes. Choosing an item from Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). 198 Nitrocellulose solutions containing not more than 20% nitrocellulose may be transported as paint, perfumery products, or printing ink, as applicable, provided the nitrocellulose contains no more 12.6% nitrogen (by dry mass). The Associate Administrator will base the authorization on results from Series 2 tests and a Series 6(c) test from the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) on packages as prepared for transport in accordance with the requirements of this subchapter. W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. ); and. Nickel-carbon asymmetric capacitors containing Class 8 alkaline electrolytes must be transported as UN2795, Batteries, wet, filled with alkali, electric storage. c. The time between offering the material for transportation at the point of origin, and unloading the material at the destination does not exceed 48 hours. 171 This entry may only be used when the material is transported in non-friable tablet form or for granular or powered mixtures that have been shown to meet the PG III criteria in 173.127. Do not enter until vapors have dissipated. The driver of the transport vehicle and the consignee(s) must be trained not to enter the transport vehicle until the ammonia vapors have dissipated, and the emergency response information on the shipping paper must indicate that the vehicle contains ammonia vapors. Additionally, each cylinder must be visually inspected in accordance with CGA pamphlet, CGA C-6 (incorporated by reference, see 171.7). Filling limits must be in accordance with portable tank special provision TP3. N91 The use of a non specification sift-proof, non-bulk, metal can with or without lid, or a non specification sift-proof, non-bulk fiber drum, with or without lid is authorized when transporting coal tar pitch compounds by motor vehicle or rail freight. 44 The formulation must be prepared so that it remains homogenous and does not separate during transport. A54 Irrespective of the quantity limits in Column 9B of the 172.101 table, a lithium battery, including a lithium battery packed with, or contained in, equipment that otherwise meets the applicable requirements of 173.185, may have a mass exceeding 35 kg if approved by the Associate Administrator prior to shipment. Additionally, the offeror must notify the carrier if the tank pressure rise exceeds 3 psig over any 24-hour period. 365 For manufactured instruments and articles containing mercury, see UN3506. The only tank car tanks authorized are Class DOT 105 tank cars having a test pressure of 2,069 kPa (300 psig) or greater. (vi) Except when an organic peroxide is authorized under 173.225(g), if a hazardous material is not assigned a portable tank T Code, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator. (3) Damage to terminals. ; and. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by 180.605 of this subchapter must be conducted. When there is an entry in this column, refer to Section 172.102 of the federal regulations for specific information. TP38 Each portable tank must be insulated with an insulating material so that the overall thermal conductance at 15.5 C (60 F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. A8 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with cushioning material in tightly closed metal receptacles before packing in outer packagings. Each empty bottle must have a minimum weight of not less than 140 grams and a minimum wall thickness of not less than 0.020 inch (0.508 mm). Regulation Y Portable tanks containing solidified methacrylic acid must not be reheated during transportation. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. Except for transportation by aircraft, as an inner packaging of a combination packaging with a maximum net mass of 40 kg (88 pounds). 1 CFR 1.1 However, the hazard label corresponding to the hazard class or division may be substituted for the marking. The requirements of 173.24(g)(1) and 173.27(c) do not apply. 12 In concentrations greater than 40 percent, this material has strong oxidizing properties and is capable of starting fires in contact with combustible materials. Unlined tanks must be passivated before being placed in service. B35 Tank cars containing hydrogen cyanide may be alternatively marked Hydrocyanic acid, liquefied if otherwise conforming to marking requirements in subpart D of this part. In addition, the column 5 reference is modified to read III on those occasions when this material is offered for transportation or transported by highway or rail. No more than four bottles, securely closed with threaded caps, may be packed in each box. In addition to the packaging required in 173.4a, each glass inner packaging must be placed in a sealed plastic bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner packaging; and. 49 CFR 172.101 For transportation by aircraft, as an inner packaging of a combination packaging with a maximum gross mass of 30 kg when packaged as a limited quantity in accordance with 173.27(f). In addition, for solid materials, special provision B54 applies. They will appear as a list of codes that are defined in 172.102 of the Code of Federal Regulations. B77 Other packaging are authorized when approved by the Associate Administrator. The chemical under pressure must be classed based on the hazard characteristics of the components in the propellant; the liquid; or the solid. A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appropriate identification number as required by subpart D of this part. 117 If shipment of the explosive substance is to take place at a time that freezing weather is anticipated, the water contained in the explosive substance must be mixed with denatured alcohol so that freezing will not occur. A210 This substance is forbidden for transport by air. 54 Maneb or maneb preparations not meeting the definition of Division 4.3 or any other hazard class are not subject to the requirements of this subchapter when transported by motor vehicle, rail car, or aircraft. 379 When offered for transport by highway, rail, or cargo vessel, anhydrous ammonia adsorbed or absorbed on a solid contained in ammonia dispensing systems or receptacles intended to form part of such systems is not subject to the requirements of this subchapter if the following conditions in this provision are met. This entry does not apply to capacitors that by design maintain a terminal voltage (e.g., asymmetrical capacitors.). (3) A flammable gas is a gas that meets the criteria in 173.115 of this subchapter. site when drafting amendatory language for Federal regulations: Get the latest updates, news, and regulations for HazMat Transport and Waste Management. Large Packagings are authorized for the Packing Group III entries of specific proper shipping names when either special provision IB3 or IB8 is assigned to that entry in the 172.101 Table. N77 For materials of not more than two percent active ingredients by weight, packagings need not conform to the requirements of part 178 of this subchapter, if liquid contents are absorbed in an inert material. Size of marking on bulk package must conform to 172.302(b) of this subchapter. These special provisions are in addition to the standard packaging requirements. 362 This entry applies to liquids, pastes or powders, pressurized with a propellant that meets the definition of a gas in 173.115. A9 For combination packagings, if plastic bags are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. metal other than steel or aluminum (50N). Any glass inner packaging showing evidence of leakage, distortion or other defect under this test must not be transported under the terms of this special provision; b. IBCs are only authorized if approved by the Associate Administrator. The presence of a Class 8 hazard must be communicated as required by this part for subsidiary hazards. The standards for transporting a single bulk hazardous material for blasting by cargo tank motor vehicles (CTMV); and. The article, machinery, or apparatus, if unpackaged, or the packaging in which it is contained shall be marked Dangerous goods in articles or Dangerous goods in machinery or Dangerous goods in apparatus as appropriate, with the identification number UN3363. e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle. N6 Battery fluid packaged with electric storage batteries, wet or dry, must conform to the packaging provisions of 173.159 (g) or (h) of this subchapter. Insulation must be at least 100 mm (3.9 inches) except that the insulation thickness may be reduced to 51 mm (2 inches) over the exterior heater coils. A combination packaging consisting of a 4G fiberboard box with inner receptacles of glass or earthenware; b. Each IBC may not exceed a maximum net quantity of 1,000 kg: a. 38 If this material shows a violent effect in laboratory tests involving heating under confinement, the labeling requirements of Special Provision 53 apply, and the material must be packaged in accordance with packing method OP6 in 173.225 of this subchapter. b. 5. If appropriate, a package containing this material must conform to the additional labeling requirements of 172.402 of this subchapter. 118 This substance may not be transported under the provisions of Division 4.1 unless specifically authorized by the Associate Administrator (see UN0143 or UN0150 as appropriate). The letter codes are placed in front of the number codes (for example, "A29"). Effective January 1, 2014, for transportation domestically by highway or rail, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. (9) A code containing the letter W refers to a special provision that applies only to transportation by water. Column 7 of the 172.101 Hazmat Table lists the special provisions that apply to an individual proper shipping name. The table follows: [Portable tank codes T1-T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in portable tanks.]. d. Receptacles containing adsorbed or absorbed ammonia shall meet the following conditions: (1) Receptacles shall be made of a material compatible with ammonia as specified in ISO 11114-1:2012(E) and ISO 11114-1:2012/Amd 1:2017(E) (IBR, see 171.7 of this subchapter); (2) Receptacles and their means of closure shall be hermetically sealed and able to contain the generated ammonia; (3) Each receptacle shall be able to withstand the pressure generated at 85 C (185 F) with a volumetric expansion no greater than 0.1%; (4) Each receptacle shall be fitted with a device that allows for gas evacuation once pressure exceeds 15 bar (1500 kPa) without violent rupture, explosion or projection; and. 368 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN3507 or UN2978. Multiple provisions can be listed in this column. Comparative fire testing between a package as prepared for transport (including the substance to be transported) and an identical package filled with water must show that the maximum temperature measured inside the packages during testing does not differ by more than 200 C (392 F). See Batteries, dry, sealed, n.o.s. in the 172.101 Hazardous Materials Table (HMT) of this part for transportation requirements for nickel-metal hydride batteries transported by other modes and for nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel. d. In addition to the training requirements prescribed in 172.700 through 172.704, each driver must be trained regarding the properties and hazards of diatomaceous earth filter material, precautions to ensure safe transport of the material, and actions to be taken in the event of an emergency during transportation, or a substantial delay in transit. All openings must be closed with gasketed blank flanges or vapor tight threaded closures. A60 Sterilization devices, when containing less than 30 mL per inner packaging with not more than 150 mL per outer packaging, may be transported in accordance with the provisions in 173.4a, irrespective of 173.4a(b), provided such packagings were first subjected to comparative fire testing. 173 For adhesives, printing inks, printing ink-related materials, paints, paint-related materials, and resin solutions which are assigned to UN3082, and do not meet the definition of another hazard class, metal or plastic packaging for substances of packing groups II and III in quantities of 5 L (1.3 gallons) or less per packaging are not required to meet the UN performance package testing when transported: a. The cylinder must be transported in a closed motor vehicle displaying FLAMMABLE GAS placards in accordance with subpart F of part 172 of this subchapter. Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. The suitability for transport in tanks must be demonstrated using test 8(d) in Test Series 8 (see UN Manual of Tests and Criteria, Part 1, Sub-section 18.7) (IBR, see 171.7 of this subchapter) or an alternative means approved by the Associate Administrator. A200 These articles must be transported as cargo and may not be carried aboard an aircraft by passengers or crewmembers in carry-on baggage, checked baggage, or on their person unless specifically authorized in 175.10. 380 For transportation by private carrier in a motor carrier only, this material is not subject to the segregation requirements of 177.848(d) of this subchapter under the following conditions: a. (a) The Hazardous Materials Table . "Published Edition". Column 8 All special provision TP26 The heating device must be exterior to the shell. 15, 1976, unless otherwise noted. B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. Column 1 uses six symbols to identify hazardous materials with special shipping conditions such as restrictions for air, domestic, international, or water vessel transport. Placards may be displayed for a hazardous material, even when not required, if the placarding otherwise conforms to the requirements of Subpart F of Part 172 [172.502(c)]. B4 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and, (1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or, (2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or. The proper shipping name Paint related material, corrosive, flammable may be used for consignments of packages containing Paint, corrosive, flammable and Paint related material, corrosive, flammable in the same package; c. The proper shipping name Paint related material, flammable, corrosive may be used for consignments of packages containing Paint, flammable, corrosive and Paint related material, flammable, corrosive in the same package; and. 369 In the case of non-fissile or fissile-excepted uranium hexafluoride, the material must be classified under UN 2978. The means of protection must be approved by the approval agency designated to approve the portable tank in accordance with the procedures in part 107, subpart E, of this subchapter. Transport vehicles must be vented to prevent accumulation of vapors at a poisonous or flammable concentration. will also bring you to search results. For continued use of approvals dated prior to January 1, 2012, see 173.308(b)(5). (See 173.50 of this subchapter.). 238 Neutron radiation detectors: Neutron radiation detectors containing non-pressurized boron trifluoride gas in excess of 1 gram (0.035 ounces) and radiation detection systems containing such neutron radiation detectors as components may be transported by highway, rail, vessel, or cargo aircraft in accordance with the following: a. d. The proper shipping name Printing ink related material may be used for consignments of packages containing Printing ink and Printing ink related material in the same package. See UN1210, UN1263, UN1266, UN3066, UN3469, and UN3470. You can These entries include hybrid electric vehicles powered by a fuel cell engine, an internal combustion engine, and batteries. (1) Numeric provisions. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries. If a package contains both lithium metal batteries and lithium ion batteries packed with and contained in equipment, then the shipping paper must indicate both UN 3091 Lithium metal batteries packed with equipment and UN 3481 Lithium ion batteries packed with equipment.. (5) Each receptacle shall be able to withstand a pressure of 20 bar (2000 kPa) without leakage when the pressure relief device is deactivated. In addition, packages shall be legibly and durably marked with an identification of the consignor, the consignee, or both. 172-123, 55 FR 52582, Dec. 21, 1990]. Organization and Purpose Column 5 references applicable requirements for bottom openings in part 178 of this subchapter. On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1 (IBR, see 171.7 of this subchapter), nitrocellulose membrane filters in the form in which they are to be transported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. A rocket motor to be considered nonpropulsive must be capable of unrestrained burning and must not appreciably move in any direction when ignited by any means. 115 Boosters with detonator, detonator assemblies and boosters with detonators in which the total explosive charge per unit does not exceed 25 g, and which will not mass detonate and undergo only limited propagation in the shipping package may be assigned to 1.4B classification code. When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in 172.102 of this subpart. TP27 A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. a. If you have comments or suggestions on how to improve the www.ecfr.gov website or have questions about using www.ecfr.gov, please choose the 'Website Feedback' button below. 157 When transported as a limited quantity or a consumer commodity, the maximum net capacity specified in 173.151(b)(1)(i) of this subchapter for inner packagings may be increased to 5 kg (11 pounds).
column 7 of the hazardous materials table
